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Preparation of silica‐supported polysulfoalumoxane–platinum complexes and their catalytic activity in the hydrogenation of aromatics
Author(s) -
Su ShiJian,
Mao SuFen,
Chen ChunWei,
Huang MeiYu,
Jiang YingYan
Publication year - 1996
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/(sici)1099-1581(199608)7:8<707::aid-pat573>3.0.co;2-5
Subject(s) - catalysis , platinum , selectivity , materials science , metal , polymer , organic chemistry , methyl benzoate , inorganic chemistry , chemistry , metallurgy , composite material
A novel inorganic polymer, silica‐supported polysulfoalumoxane, has been prepared and used as a support for preparing a silica‐supported polysulfoalumoxane–platinum complex. It has been used as a catalyst for the hydrogenation of aromatics under mild conditions. The effects of several reaction parameters such as metal loading, temperature and solvents on the hydrogenation of methyl benzoate have been studied. The catalyst showed high activity and selectivity.