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Morphology control at phase separation of curing multicomponent thermosets
Author(s) -
Rozenberg Boris A.,
Sigalov Grigory M.
Publication year - 1996
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/(sici)1099-1581(199605)7:5/6<356::aid-pat494>3.0.co;2-e
Subject(s) - thermosetting polymer , curing (chemistry) , materials science , phase boundary , non equilibrium thermodynamics , phase equilibrium , phase (matter) , thermodynamics , chemical engineering , process engineering , composite material , organic chemistry , chemistry , engineering , physics
The process of phase separation in the course of the thermoset curing reaction is considered. Clarification of the role of kinetic factors in such processes is the focus of the article, and the need in a kinetic theory for cure reaction‐induced phase separation (CRIPS) is substantiated. An adequate nonequilibrium approach proposed previously is given further development. A new CRIPS model with equilibrium boundary conditions is introduced.