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Separation of xylenols by inclusion
Author(s) -
Caira Mino R.,
Nassimbeni Luigi R.,
Vujovic Dejana,
Toda Fumio
Publication year - 2000
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/(sici)1099-1395(200001)13:1<75::aid-poc193>3.0.co;2-a
Subject(s) - chemistry , cyclohexane , inclusion (mineral) , selectivity , host (biology) , organic chemistry , mineralogy , ecology , catalysis , biology
The host 1,1‐bis(4‐hydroxyphenyl)cyclohexane, H , forms 1:1 inclusion compounds with 2,3‐xylenol, Hċ23X , and with 3,5‐xylenol, Hċ35X . Competition experiments were conducted to determine the host selectivity toward three xylenol isomers, 2,3‐, 3,5‐ and 2,6‐xylenol. The structure of the solid formed between H and a mixture of 23X and 35X was elucidated. Copyright © 2000 John Wiley & Sons, Ltd.