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Hydrolysis of N ‐methyl‐ N ‐nitroso‐ p ‐toluenesulphonamide in micellar media
Author(s) -
GarcíaRío L.,
Hervés P.,
Leis J. R.,
Mejuto J. C.,
PerezJuste J.
Publication year - 1998
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/(sici)1099-1395(199808/09)11:8/9<584::aid-poc59>3.0.co;2-f
Subject(s) - chemistry , micelle , nitroso , reaction rate constant , hydrolysis , reactivity (psychology) , kinetic energy , medicinal chemistry , micellar solutions , kinetics , organic chemistry , aqueous solution , medicine , physics , alternative medicine , pathology , quantum mechanics
The acid and basic hydrolysis of N ‐methyl‐ N ‐nitroso‐ p ‐toluenesulphonamide (MNTS) was studied in different micellar aggregates (CTACl, CTABr, TTABr, LTABr, and OTACl). The effect of mixed micelles (OTAX–LTAX) was also studied. The kinetic behaviour was explained on the basis of the pseudophase model, from which the binding constants of MNTS to different micelles, the ion exchange constants and the reactivity constants in the micellar pseudophase were obtained. © 1998 John Wiley & Sons, Ltd.