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Oxidation of allyl alcohol by alkaline periodate in the presence of micro amounts of palladium(II)
Author(s) -
Hiremath Gouri A.,
Timmanagoudar Prakash L.,
Nandibewoor Sharanappa T.
Publication year - 1998
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/(sici)1099-1395(199801)11:1<31::aid-poc968>3.0.co;2-7
Subject(s) - chemistry , periodate , catalysis , allyl alcohol , palladium , alcohol , alkali metal , substrate (aquarium) , alcohol oxidation , inorganic chemistry , medicinal chemistry , polymer chemistry , organic chemistry , oceanography , geology
The oxidation of allyl alcohol by alkaline species of periodate, H 2 IO 6 3− , was found to be catalysed by micro amounts of Pd(II) in 0.2 mol dm −3 alkali solution. The active species of the catalyst was found to be PdCl + . A mechanism involving the interaction of the catalyst and substrate in prior equilibria leading to the formation of a π‐complex is proposed and the rate is derived. © 1998 John Wiley & Sons, Ltd.