X‐ray and vibrational studies of 8‐aminoquinoline. Evidence for a three‐center hydrogen bond | Zendy

Van Meervelt L. | Zendy; Goethals M. | Zendy; Leroux N. | Zendy; ZeegersHuyskens Th. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

X‐ray and vibrational studies of 8‐aminoquinoline. Evidence for a three‐center hydrogen bond

Author(s) -

Van Meervelt L.,

Goethals M.,

Leroux N.,

ZeegersHuyskens Th.

Publication year - 1997

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/(sici)1099-1395(199709)10:9<680::aid-poc902>3.0.co;2-y

Subject(s) - chemistry , hydrogen bond , intramolecular force , intermolecular force , raman spectroscopy , low barrier hydrogen bond , triple bond , hydrogen , crystallography , stereochemistry , computational chemistry , molecule , polymer chemistry , double bond , organic chemistry , physics , optics

The x‐ray structure of 8‐aminoquinoline indicates that one of the NH bonds of the NH 2 group forms a three‐center hydrogen bond, the major component being the intramolecular hydrogen bond and the minor component the intermolecular hydrogen bond. The IR and Raman spectra of 8‐aminoquinoline and of its N ‐deuterated counterpart reflect the non‐equivalence of the two NH(D) bonds and the weakness of the hydrogen bridge. © 1997 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research