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Carbonylmetallates and carbanions in aromatic and vinylic nucleophilic substitution
Author(s) -
Beletskaya I. P.,
Artamkina G. A.,
Mil'chenko A. Yu.,
Sazonov P. K.,
Shtern M. M.
Publication year - 1996
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/(sici)1099-1395(199606)9:6<319::aid-poc786>3.0.co;2-7
Subject(s) - carbanion , chemistry , reactivity (psychology) , nucleophile , nucleophilic substitution , substitution reaction , medicinal chemistry , transition metal , organic chemistry , catalysis , medicine , alternative medicine , pathology
The kinetic data on the reactions of carbonylmetallates M′M(CO) n L m , with polyfluorinated arenes and alkenes are reported. The behaviour of these transition metal anionic nucleophiles is compared with the reactivity of both carbanions, and non‐transition metal centred anions.