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Some reactions of zerovalent metals with aqueous organometal(loid)s
Author(s) -
Thayer John S.
Publication year - 1998
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/(sici)1099-0739(199808/09)12:8/9<571::aid-aoc764>3.0.co;2-p
Subject(s) - chemistry , aqueous solution , dissolution , inorganic chemistry , kinetics , bromide , zerovalent iron , metal , zero order , aqueous medium , nuclear chemistry , first order , organic chemistry , adsorption , physics , quantum mechanics , mathematics
Aqueous solutions of bromoalkyltriphenylphosphonium bromides react with zerovalent metals, causing their dissolution. The reaction initially follows second‐order kinetics, with the rate depending on both metal and bromide concentrations. Zerovalent metals similarly react with aqueous methylmercuric acetate and other dissolved organometals. © 1998 John Wiley & Sons, Ltd.