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Low‐Temperature Chemical Approaches for Synthesizing Sulfides and Nitrides of Reactive Transition Metals
Author(s) -
Sriram M. A.,
Weil K. S.,
Kumta P. N.
Publication year - 1997
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/(sici)1099-0739(199702)11:2<163::aid-aoc564>3.0.co;2-s
Subject(s) - chemistry , oxide , sol gel , nitride , ternary operation , transition metal , ceramic , sulfide , fourier transform infrared spectroscopy , chemical engineering , inorganic chemistry , nanotechnology , catalysis , organic chemistry , materials science , layer (electronics) , computer science , engineering , programming language
The advent of the sol–gel technique over the past several decades and the recognition of its excellent flexibility for synthesizing a large variety of oxide ceramics and glasses in both bulk and thin‐film forms has generated considerable interest in using solution‐based processes to prepare ceramic materials. Because of the success of the sol–gel technique, a number of other chemical processes have been developed utilizing metalorganic/organometallic starting materials to create molecularly architectured precursors, which have proven effective in synthesizing both oxide and non‐oxide materials. In the present study, two different chemical approaches have been implemented to synthesize non‐oxides (sulfides and nitrides) of reactive transition‐metal elements. Accordingly, a novel thio‐sol–gel process for preparing TiS 2 and NbS 2 powders has been studied. In the case of TiS 2 synthesis, the chemical reaction has been examined in detail using Fourier‐transform infrared spectroscopy (FTIR) and gas chromatography (GC). The effects of modification of the titanium precursor on the morphology of the final sulfide have also been investigated and are discussed. A second, more generalized process has been developed for synthesizing homogeneous precursors in multicomponent systems. Its utilization in preparing ternary nitrides has been demonstrated, and is also presented. © 1997 by John Wiley & Sons, Ltd.