Premium
Synthesis of Oligomeric Axially Bridged Ruthenium Phthalocyanines and 2,3‐Naphthalocyanines
Author(s) -
Knecht Siegfried,
Polley Rainer,
Hanack Michael
Publication year - 1996
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/(sici)1099-0739(199610)10:8<649::aid-aoc525>3.0.co;2-k
Subject(s) - chemistry , ruthenium , solid state , axial symmetry , nuclear magnetic resonance spectroscopy , polymer chemistry , spectroscopy , proton nmr , crystallography , stereochemistry , organic chemistry , catalysis , structural engineering , engineering , physics , quantum mechanics
Bridged 2,3‐naphthalocyaninatoruthenium oligomers {[MacRu(L)] n } were synthesized and characterized using solid‐state methods. For comparison, soluble t‐butyl substituted phthalocyaninatoruthenium oligomers were prepared and their chain length examined by 1 H NMR spectroscopy. The powder conductivities of all bridged compounds ([MacRu(L)] n ) were measured and the dependence of the conductivities on the bridging ligands is discussed.