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Synthesis and Crystal Structure of Bis(2,3‐dihydro‐3‐methylbenzothiazole‐2‐ylidene)palladium(II) Diiodide: The First Palladium Complex with Benzothiazole Carbene Ligands Suitable for Homogeneous Catalysis
Author(s) -
Caló Vincenzo,
Sole Roberta Del,
Nacci Angelo,
Schingaro Emanuela,
Scordari Fernando
Publication year - 2000
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(200003)2000:6<869::aid-ejoc869>3.0.co;2-i
Subject(s) - palladium , chemistry , benzothiazole , carbene , catalysis , nucleophile , homogeneous catalysis , crystal structure , medicinal chemistry , heck reaction , combinatorial chemistry , organic chemistry
The first diiodo palladium complex with nucleophilic benzothiazole carbenes as ligands has been synthesized and characterized. The complex, which is extraordinarily stable towards heat, oxygen, and moisture, has been found to show good catalytic activity in the Heck coupling reaction.