Premium
Studies on the Mercury‐Desilylation of Chiral Cyclopropylmethylsilanes ‐ A Stereocontrolled Access to Carba‐Sugars
Author(s) -
Landais Yannick,
ParraRapado Liliana
Publication year - 2000
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(200002)2000:3<401::aid-ejoc401>3.0.co;2-m
Subject(s) - chemistry , stereospecificity , mercury (programming language) , enantioselective synthesis , stereochemistry , combinatorial chemistry , organic chemistry , catalysis , computer science , programming language
Mercury‐desilylation of cyclopropylmethylsilanes affords a stereospecific access to homoallylic mercury intermediates, which can be elaborated further. This strategy is illustrated with a short access to carba‐furanoses and carba‐C‐disaccharides.