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The Highly Selective Oxidation of a Tricarbonyliron Complex
Author(s) -
Fischer Jürgen,
Jones Peter G.,
Nippert Uwe,
Winterfeldt Ekkehard
Publication year - 1999
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199912)1999:12<3455::aid-ejoc3455>3.0.co;2-8
Subject(s) - chemistry , ponding , alcohol oxidation , alcohol , organic chemistry , medicinal chemistry , combinatorial chemistry , ecology , drainage , biology
The tricarbonyliron complex 2a underwent selective and diastereoselective oxidation with tert ‐butyl hydroperoxide at room temperature to provide, after decomplexation, the peroxyether 5 which, on reduction, yielded the corres‐ponding secondary alcohol 7 .