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Direct Synthesis of Stable Adamantylideneadamantane Bromonium Salts
Author(s) -
Bortolini Olga,
Chiappe Cinzia,
Conte Valeria,
Carraro Mauro
Publication year - 1999
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199912)1999:12<3237::aid-ejoc3237>3.0.co;2-c
Subject(s) - chemistry , derivative (finance) , organic chemistry , tribromide , computational chemistry , medicinal chemistry , economics , financial economics
Abstract By using a V V ‐ or Mo VI ‐catalyzed two‐phase procedure for oxybromination of organic substrates, adamantylideneadamantane bromonium salts (ADABr + X – ; X – = V V ‐ and Mo VI ‐containing anions) have been isolated and characterized. These salts proved to be significantly more stable relative to the corresponding tribromide derivative.