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Conformation Control in Open‐Chain Compounds with up to Six Rotatable Bonds
Author(s) -
Stenkamp Dirk,
Hoffmann Reinhard W.,
Göttlich Richard
Publication year - 1999
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199911)1999:11<2929::aid-ejoc2929>3.0.co;2-1
Subject(s) - vicinal , chemistry , substituent , alkane , stereochemistry , chain (unit) , organic chemistry , hydrocarbon , physics , astronomy
Substituent patterns on 1,3,5…‐polyoxygenated‐2,4,6…‐polymethylated alkane chains, which preferentially adopt a fully extended backbone conformation, have been identified. This is demonstrated by analysis of the vicinal H,H‐coupling constants along the backbones of compounds 19 , 23 , and 24 .