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Preparation and NMR Investigation of 1,2‐Distannyl Aromatics and Heteroaromatics, 1,2‐Distannylcycloalkenes and 1,2‐Distannylcycloalkanes
Author(s) -
Mitchell Terence N.,
Böttcher Karin,
Bleckmann Paul,
Costisella Burkhard,
Schwittek Christoph,
Nettelbeck Christa
Publication year - 1999
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199909)1999:9<2413::aid-ejoc2413>3.0.co;2-0
Subject(s) - chemistry , diimine , organic chemistry , carbon 13 nmr , proton nmr , catalysis
A series of 1,2‐distannylated aromatics, heteroaromatics and cycloalkenes was prepared by treating the dibromo precursors with Me 3 SnNa in tetraglyme. The latter were converted into the corresponding cycloalkanes by diimine reduction. Multinuclear NMR data are reported and discussed.