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Rapid Marcus Curvature Due to Extremely Strong Solvational Imbalances inthe Deprotonation of a Trinitrobenzylic Carbon Acid by Oximate Bases
Author(s) -
Terrier François,
Moutiers Gilles,
Pelet Sandrie,
Buncel Erwin
Publication year - 1999
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199908)1999:8<1771::aid-ejoc1771>3.0.co;2-p
Subject(s) - deprotonation , chemistry , reactivity (psychology) , proton , curvature , term (time) , carbon fibers , medicinal chemistry , ion , organic chemistry , physics , geometry , computer science , quantum mechanics , algorithm , medicine , alternative medicine , mathematics , pathology , composite number
We report the first instance of the levelling of oximate reactivity in a deprotonation process, which is shown to have as origin the desolvation of the oximate ion prior to actual proton transfer, in accord with the large predominance of the work term ( w r ) far exceeding the intrinsic barrier term in the Marcus formulation.