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New Water‐Soluble Diamine Complexes as Catalysts for the Hydrogenation of Ketones Under Hydrogen Pressure
Author(s) -
Pénicaud Virginie,
Maillet Céline,
Janvier Pascal,
Pipelier Muriel,
Bujoli Bruno
Publication year - 1999
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199907)1999:7<1745::aid-ejoc1745>3.0.co;2-b
Subject(s) - chemistry , rhodium , catalysis , iridium , hydrogen , diamine , aqueous solution , water soluble , organic chemistry , aqueous medium , polymer chemistry
Abstract New water‐soluble rhodium and iridium complexes of 2,2′‐bipyridines, functionalized with PO 3 Na 2 groups, show very good catalytic activities in the reduction of various substituted acetophenones under hydrogen pressure in basic aqueous media. No significant loss of catalyst activity is observed after one use.