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Synthesis and Structural Characterisation of Cyclohexylamine Hemihydrochloride
Author(s) -
Jones Peter G.,
Ahrens Birte
Publication year - 1998
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199808)1998:8<1687::aid-ejoc1687>3.0.co;2-y
Subject(s) - cyclohexylamine , chemistry , hydrogen bond , molecule , amine gas treating , salt (chemistry) , organic chemistry , crystallography
The first structural characterization of a simple aliphatic amine ‘hemi’ salt is reported: cyclohexylamine hemihy‐drochloride. An X‐ray structure determination reveals that a cyclohexylammonium cation and a cyclohexylamine molecule are linked by a hydrogen bond N + –H···N. Further H bonds N–H···Cl lead to a layer structure.