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Deaminative Fluorination of Anilines with Silicon Tetrafluoride: Utility of Silicon Tetrafluoride as a Fluorine Source
Author(s) -
Tamura Masanori,
Shibakami Motonari,
Sekiya Akira
Publication year - 1998
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199804)1998:4<725::aid-ejoc725>3.0.co;2-r
Subject(s) - chemistry , tetrafluoride , fluorine , silicon , inorganic chemistry , organic chemistry , molecule
Application of silicon tetrafluoride to deaminative fluorination of anilines as a fluorine source is investigated. A diazotization of anilines proceeds with silicon tetrafluoride and t ‐butyl nitrite under mild condition and the following fluoro‐dediazoniation affords fluoroarenes in good yields.