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Unprecedented 1,3‐Dipolar Cycloaddition of Azomethine Ylides Derived from Difluorocarbene and Imines to Carbonyl Compounds. − Synthesis of Oxazolidine Derivatives
Author(s) -
Novikov Mikhail S.,
Khlebnikov Alexander F.,
Krebs Adolf,
Kostikov Rafael R.
Publication year - 1998
Publication title -
european journal of organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.825
H-Index - 155
eISSN - 1099-0690
pISSN - 1434-193X
DOI - 10.1002/(sici)1099-0690(199801)1998:1<133::aid-ejoc133>3.0.co;2-u
Subject(s) - difluorocarbene , oxazolidine , chemistry , cycloaddition , 1,3 dipolar cycloaddition , azomethine ylide , organic chemistry , photochemistry , catalysis
Iminiodifluoromethanides generated by the reaction of difluorocarbene with benzaldehyde and benzophenone imines undergo regioselective 1,3‐dipolar cycloaddition to aldehydes to give oxazolidine derivatives.

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