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New Silyl‐Substituted Tin‐Nitrogen Heterocubanes: Fourfold Metal‐Coordinated Nitrogen and Exceptional Chemical and NMR Properties
Author(s) -
Veith Michael,
Opsölder Michael,
Zimmer Michael,
Huch Volker
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(200006)2000:6<1143::aid-ejic1143>3.0.co;2-q
Subject(s) - chemistry , tin , silylation , nitrogen , metal , nuclear magnetic resonance spectroscopy , inorganic chemistry , chemical shift , organic chemistry , catalysis
The synthesis of new silyl‐substituted tin‐nitrogen heterocubanes and the structural analysis of [Me 3 SiNSn] 4 is described. A sharp signal in the 14 N NMR spectrum and a septet in the 119 Sn NMR spectrum are among the interesting properties of this new type of compound with nitrogen surrounded by four (hemi)metals.