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Novel Nitrido‐ and Oxo(phthalocyaninato) Complexes of Molybdenum, Tungsten and Rhenium
Author(s) -
Frick Karsten,
Verma Sanjiv,
Sundermeyer Jörg,
Hanack Michael
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(200005)2000:5<1025::aid-ejic1025>3.0.co;2-s
Subject(s) - rhenium , chemistry , molybdenum , tungsten , diamagnetism , inorganic chemistry , polymer chemistry , medicinal chemistry , stereochemistry , crystallography , organic chemistry , physics , quantum mechanics , magnetic field
The synthesis of new nitrido(phthalocyaninato)molybdenum ( 1 – 4 ) and ‐tungsten complexes ( 5 – 7 ) starting from the corresponding phthalonitriles and MNCl 3 (M = Mo, W) is reported. In addition, the reaction of ( t Bu 4 Pc)WN ( 6 ) with PPh 3 leading, after several steps, to the diamagnetic compound ( t Bu 4 Pc)WO ( 7 ) is described. The reaction of ( t Bu 4 Pc)ReN ( 9 ) with PPh 3 leads to [( t Bu 4 Pc)ReO] 2 ( 12 ), and of [(C 5 H 11 ) 8 Pc]ReN ( 10 ) with PPh 3 leads, under different conditions, to {[(C 5 H 11 ) 8 Pc]ReO} 2 O ( 11 ).