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Trinuclear Palladium(II) Complexes with 2‐Hydroxy‐4‐methoxyacetophenone N 4 ‐Dimethylthiosemicarbazone: Synthesis, Spectral Studies and Crystal Structure of a Tripalladium Complex
Author(s) -
KovalaDemertzi Dimitra,
Kourkoumelis Nikolaos,
Demertzis Mavroudis A.,
Miller John R.,
Frampton Christopher S.,
Swearingen John K.,
West Douglas X.
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(200004)2000:4<727::aid-ejic727>3.0.co;2-r
Subject(s) - chemistry , palladium , crystal structure , moiety , imine , semicarbazone , crystallography , stereochemistry , crystal (programming language) , catalysis , organic chemistry , computer science , programming language
The synthesis and spectral characterization of a new triangular , trinuclear palladium(II) complex with the dianion of 2‐hydroxy‐4‐methoxyacetophenone N 4 ‐dimethylthiosemicarbazone, 4MeOAp4Me 2 2–is reported. The X‐ray crystal structure determination of [Pd(4MeOAp4Me 2 )] 3 · DMSO shows it to contain a chair‐type hexagon of alternating Pd and S atoms which form a molecular bowl. The crystal structure of H 2 4MeOAp4Me 2 shows that it is the E isomer with respect to the imine bond of the thiosemicarbazone moiety.