Premium
Novel Organometallic Derivatives of Thioesters of the Trivalent Phosphorus Acids: Synthesis and Structure
Author(s) -
Milyukov Vasily A,
Zverev Alexander V.,
Podlesnov Sergey M.,
Krivolapov Dmitry B.,
Litvinov Igor A.,
Gubaidullin Aidar T.,
Kataeva Olga N.,
Ginzburg Allan G.,
Sinyashin Oleg G.
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(200001)2000:1<225::aid-ejic225>3.0.co;2-u
Subject(s) - chemistry , white phosphorus , phosphorus , lone pair , sulfur , group 2 organometallic chemistry , oxygen atom , stereochemistry , crystallography , inorganic chemistry , medicinal chemistry , organic chemistry , molecule
Thioesters of the phosphorous acid containing cymantrenyl and ferrocenyl substituents at sulfur were obtained for the first time from the reaction of organometallic disulfides with white phosphorus. According to an X‐ray diffraction study tricymantrenyl trithiophosphite adopts an unusual asymmetric cis , gauche , trans conformation along the P–S bonds with respect to the phosphorus lone electron pair. Triferrocenyl trithiophosphate possesses a classical propeller‐like structure in the solid state which is different from its oxygen analogue.