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Microwave‐Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin‐Type Polyoxotungstates: One‐Step Synthesis, 99 Ru, 183 W NMR Characterization and Catalytic Activity of [PW 11 O 39 Ru II (DMSO)] 5–
Author(s) -
Bagno Alessandro,
Bonchio Marcella,
Sartorel Andrea,
Scorrano Gianfranco
Publication year - 2000
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(200001)2000:1<17::aid-ejic17>3.0.co;2-#
Subject(s) - lacunary function , chemistry , ruthenium , catalysis , characterization (materials science) , nanotechnology , organic chemistry , materials science , mathematics , pure mathematics
Microwave irradiation for 15 minutes allowed the highly selective hydrothermal synthesis of the diamagnetic, air‐stable oxidation catalyst [PW 11 O 39 Ru II (DMSO)] 5– , as confirmed by 1 H, 31 P, 99 Ru and 183 W NMR techniques.