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Synthesis and Structure of the First Fullerene Complex of Titanium Cp 2 Ti(η 2 ‐C 60 )
Author(s) -
Burlakov V. V.,
Usatov A. V.,
Lyssenko K. A.,
Antipin M. Yu.,
Novikov Yu. N.,
Shur V. B.
Publication year - 1999
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199911)1999:11<1855::aid-ejic1855>3.0.co;2-s
Subject(s) - chemistry , fullerene , titanium , toluene , acetylene , derivative (finance) , trimethylsilyl , argon , diffraction , fullerene chemistry , photochemistry , organic chemistry , physics , financial economics , optics , economics
The first fullerene complex of titanium Cp 2 Ti(η 2 ‐C 60 ) has been synthesized by reaction of the bis(trimethylsilyl)‐acetylene complex of titanocene Cp 2 Ti(η 2 ‐Me 3 SiC 2 SiMe 3 ) with an equimolar amount of fullerene‐60 in toluene at room temperature under argon. An X‐ray diffraction study of the complex has shown that it has the structure of a titanacyclopropane derivative.