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Formation and Structural Characterisation of an Unusual Cyclic HexamericOxotitanium Complex
Author(s) -
Kemmitt Tim,
AlSalim Najeh I.,
Gainsford Graeme J.
Publication year - 1999
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199911)1999:11<1847::aid-ejic1847>3.0.co;2-i
Subject(s) - chemistry , alkoxide , octahedron , hydrolysis , ligand (biochemistry) , crystallography , x ray crystallography , oxide , ring (chemistry) , diffraction , complex oxide , stereochemistry , organic chemistry , crystal structure , receptor , catalysis , biochemistry , physics , optics
Ti 6 O 6 (MDEA) 6 ·2CH 2 Cl 2 (MDEA = N ‐methyldiethoxoamine) was obtained by the controlled hydrolysis of the Ti(MDEA) 2 complex and analysed by X‐ray diffraction. The compound consists of a ring of six [TiO 5 N] octahedra, edge bridged by μ 2 ‐oxide and a μ 2 ‐alkoxide arm of the aminoalkoxide ligand.