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Gas‐Phase Characterization of an Unhindered Germaimine by UV‐Photoelectron Spectroscopy
Author(s) -
Foucat Séverine,
Pigot Thierry,
PfisterGuillouzo Geneviève,
Mazières Stéphane,
Lavayssière Hélène
Publication year - 1999
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199907)1999:7<1151::aid-ejic1151>3.0.co;2-2
Subject(s) - chemistry , x ray photoelectron spectroscopy , lone pair , spectroscopy , nitrogen , flash vacuum pyrolysis , gas phase , ultraviolet photoelectron spectroscopy , nitrogen atom , phase (matter) , characterization (materials science) , pyrolysis , crystallography , analytical chemistry (journal) , photochemistry , electronic structure , computational chemistry , nanotechnology , molecule , group (periodic table) , organic chemistry , nuclear magnetic resonance , physics , quantum mechanics , materials science
An unhindered germaimine has been generated and characterized by the coupling of flash vacuum pyrolysis of two different precursors with UV‐photoelectron spectroscopy. The Ge=N unit exhibits two ionizations in the low‐energy region, corresponding to the ejection of an electron from the nitrogen atom lone pair and from the π Ge=N orbital, respectively.