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Fast Palladium Catalyzed Arylation of Alkenes Using Bulky Monodentate Phosphorus Ligands
Author(s) -
F. van Strijdonck Gino P.,
Boele Maarten D. K.,
Kamer Paul C. J.,
de Vries Johannes G.,
van Leeuwen Piet W. N. M.
Publication year - 1999
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199907)1999:7<1073::aid-ejic1073>3.0.co;2-t
Subject(s) - chemistry , palladium , alkene , denticity , catalysis , oxidative addition , migratory insertion , ligand (biochemistry) , phosphorus , combinatorial chemistry , oxidative phosphorylation , heck reaction , medicinal chemistry , organic chemistry , metal , receptor , biochemistry
Complex 1b shows an unprecedented high activity in the Heck reaction. Kinetic studies show that in this system not the oxidative addition but the alkene coordination/migratory insertion is the rate determining step.