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Cobalt Complexes with 1,3‐Bis(trimethylsilyl)cyclopentadienyl and Substituent‐Free P n Ligands
Author(s) -
Scherer Otto J.,
Völmecke Thomas,
Wolmershäuser Gotthelf
Publication year - 1999
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199906)1999:6<945::aid-ejic945>3.0.co;2-i
Subject(s) - chemistry , cobalt , cyclopentadienyl complex , trimethylsilyl , substituent , white phosphorus , medicinal chemistry , crystal structure , stereochemistry , inorganic chemistry , phosphorus , catalysis , crystallography , organic chemistry
The thermal or photochemical reaction of [Cp′′Co(CO) 2 ] ( 1 ) [Cp′′ = C 5 H 3 (SiMe 3 ) 2 ‐1,3] with white phosphorus (P 4 ) gives [{Cp′′Co} 2 (P 5 –P 5 ){CoCp′′} 2 ] ( 2 ) and [{Cp′′Co} 3 P 4 (μ‐CO)] ( 3 ) as well as [{Cp′′Co} 2 (μ‐η 2 :η 2 ‐P 2 ) 2 ] ( 4 ). Cobalt complexes 2 , 3 , and 4 have been characterized by an X‐ray crystal‐structure determination.