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Synthesis and X‐ray Structure Determination of tert ‐Butylhydrazinium Azide and N,N,N ‐Trimethylhydrazinium Azide
Author(s) -
Habereder Tassilo,
Hammerl Anton,
Holl Gerhard,
Klapötke Thomas M.,
Knizek Jörg,
Nöth Heinrich
Publication year - 1999
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199905)1999:5<849::aid-ejic849>3.0.co;2-a
Subject(s) - azide , chemistry , raman spectroscopy , yield (engineering) , x ray , nuclear magnetic resonance spectroscopy , crystallography , stereochemistry , organic chemistry , metallurgy , physics , materials science , quantum mechanics , optics
tert ‐Butylhydrazinium azide [ t BuNH 2 NH 2 ] + [N 3 ] − ( 1 ) was prepared in a high yield reaction from tert ‐butylhydrazine and HN 3 . N,N,N ‐Trimethylhydrazinium azide [NH 2 N(CH 3 ) 3 ] + [N 3 ] − ( 2 ) was prepared from the reaction of silver azide with N,N,N ‐trimethylhydraziniumiodide. Both were characterized by X‐ray structural analysis, IR, Raman, and multinuclear ( 1 H, 13 C, 14 N) NMR spectroscopy.