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Diene Complexes of trans ‐5‐Palladatricyclo[4.1.0.0 2,4 ]heptanes
Author(s) -
Hashmi A. Stephen K.,
Bats Jan W.,
Naumann Frank,
Berger Bernd
Publication year - 1998
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199812)1998:12<1987::aid-ejic1987>3.0.co;2-6
Subject(s) - chemistry , norbornadiene , heptane , diene , olefin fiber , 1,5 cyclooctadiene , bridged compounds , metal , stereochemistry , cyclooctadiene , medicinal chemistry , organic chemistry , catalysis , natural rubber
The complexes rac ‐ 5 and rac ‐ 6 of the trans ‐5‐palladatricyclo[4.1.0.0 2,4 ]heptane rac ‐ 2a with norbornadiene and 1,5‐cyclooctadiene were prepared and investigated by X‐ray structure determination. With open‐chained, unsaturated substrates, e.g. 7 and 8 , no complexes could be isolated. In all cases no insertion of the olefin into the metal–carbon bond of the palladacycloalkane was observed.