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Ligand‐to‐Ligand Charge Transfer in (2,2′‐Biquinoline)bis(cyclopentadienyl)zirconium(IV) – Absorption and Emission in the Visible Range
Author(s) -
Kunkely Horst,
Vogler Arnd
Publication year - 1998
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199812)1998:12<1863::aid-ejic1863>3.0.co;2-3
Subject(s) - chemistry , cyclopentadienyl complex , ligand (biochemistry) , zirconium , absorption (acoustics) , charge (physics) , range (aeronautics) , photochemistry , inorganic chemistry , organic chemistry , receptor , biochemistry , materials science , quantum mechanics , composite material , catalysis , physics , acoustics
The lowest energy electronic transition of [(cyclopentadienyl) 2 Zr IV (2,2′‐biquinoline)] 2+ , which appears in absorption at λ max = 360 nm and in emission at λ max = 518 nm, is of the Cp − → biq ligand‐to‐ligand charge‐transfer‐type.