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Crystal Structure and Formation of the Aluminium Hydroxide Chloride [Al 13 (OH) 24 (H 2 O) 24 ]Cl 15 · 13 H 2 O
Author(s) -
Seichter Wilhelm,
Mögel HansJörg,
Brand Paul,
Salah Dhafer
Publication year - 1998
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199806)1998:6<795::aid-ejic795>3.0.co;2-a
Subject(s) - chemistry , aluminium , octahedron , crystal structure , aqueous solution , chlorine , chloride , hydroxide , aluminium hydroxide , inorganic chemistry , aluminium chloride , crystal (programming language) , crystal chemistry , crystallography , organic chemistry , computer science , programming language
A basic aluminium chloride with high chlorine content (basicity 1.85) has been crystallized from a concentrated aqueous solution. Its crystal structure has been determined by X‐ray structure analysis. The structure contains tridecameric cations of a novel type consisting only of interconnected AlO 6 octahedra. The formation of these polycations is discussed.