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An Unusual Ring Structure of an Oligomeric Oxotitanium Alkoxide Carboxylate
Author(s) -
Kickelbick Guido,
Schubert Ulrich
Publication year - 1998
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/(sici)1099-0682(199802)1998:2<159::aid-ejic159>3.0.co;2-d
Subject(s) - chemistry , alkoxide , carboxylate , ring (chemistry) , polymer chemistry , stereochemistry , organic chemistry , catalysis
Ti 9 O 8 (OPr) 4 (methacrylate) 16 was obtained by the reaction of Ti(OPr) 4 with an excess of methacrylic acid and analyzed by X‐ray diffraction. The compound consists of a ring of nine [TiO 6 ] octahedra linked by six μ 2 ‐ and only two μ 3 ‐oxide bridges.