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Synergism between Brønsted acid sites and metal sulfide particles in the hydrodesulfurization of thiophene on ultrastable Y zeolite catalysts W/USY and Ni/USY
Author(s) -
Cid Ruby,
Godoy Juan,
Neira José,
Agudo Antonio López
Publication year - 1998
Publication title -
journal of chemical technology and biotechnology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.64
H-Index - 117
eISSN - 1097-4660
pISSN - 0268-2575
DOI - 10.1002/(sici)1097-4660(199805)72:1<33::aid-jctb857>3.0.co;2-l
Subject(s) - hydrodesulfurization , thiophene , zeolite , catalysis , sulfide , brønsted–lowry acid–base theory , inorganic chemistry , chemistry , nickel sulfide , nickel , metal , tungsten , organic chemistry
The influence of the acidity of ultrastable Y (USY) zeolite‐supported tungsten or nickel sulfide catalysts, prepared at different pH values, on thiophene hydrodesulfurization activity has been studied. The acidity affects the catalysts' deactivation. The results of the initial activity clearly show a synergic effect between the metal sulfide centers and the Brønsted acid sites present in the zeolites. © 1998 SCI

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