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Polyperoxide surfactants for interface modification and compatibilization of polymer colloidal systems. I. Synthesis and properties of polyperoxide surfactants
Author(s) -
Voronov S.,
Tokarev V.,
Oduola K.,
Lastukhin Yu.
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(20000523)76:8<1217::aid-app2>3.0.co;2-f
Subject(s) - copolymer , maleic anhydride , compatibilization , polymer chemistry , ternary operation , styrene , materials science , colloid , aqueous solution , polymer , chemical engineering , chemistry , polymer blend , polymer science , organic chemistry , composite material , computer science , engineering , programming language
Anhydride‐containing polyperoxides were synthesized by copolymerization of 5− tert −butylperoxy−5−methyl−1−hexen−3−yne with either maleic anhydride or its blends with styrene. The integral composition of the polyperoxides was theoretically calculated as the copolymerization process proceeded and its direct experimental evidence was obtained. In macrochain‐formation behavior, the process was found to be consistent with the generally accepted regularities of binary and ternary copolymerization. By employing their polymerizational transformations, water‐soluble polyperoxides exhibiting surface activity and initiating properties were obtained. In aqueous solutions, such polyperoxide surfactants form micellelike colloidal structures. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 76: 1217–1227, 2000