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Polycarbazole obtained by electrochemical polymerization of monomers either in solution or in thin film form
Author(s) -
Taoudi H.,
Bernede J. C.,
Del Valle M. A.,
Bonnet A.,
Molinie P.,
Morsli M.,
Diaz F.,
Tregouet Y.,
Bareau A.
Publication year - 2000
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(20000328)75:13<1561::aid-app1>3.0.co;2-c
Subject(s) - carbazole , materials science , thin film , polymerization , scanning electron microscope , monomer , polymer chemistry , x ray photoelectron spectroscopy , chemical engineering , polymer , electrolyte , thermogravimetric analysis , electrochemistry , conductive polymer , electrode , analytical chemistry (journal) , composite material , chemistry , nanotechnology , organic chemistry , engineering
Polycarbazole has been synthesized by electrochemistry. The carbazole monomer source consists either in carbazole in solution in the electrolyte or in carbazole deposited in thin film form onto the working electrode. The two families of polymers have been studied by infrared absorption, X‐ray diffraction, thermal gravimetric analysis, scanning electron microscopy (SEM), X‐ray photoelectron spectroscopy, electron spin resonance, and electrical conductivity measurements. It is shown that the polycarbazole films obtained with carbazole deposited in the thin film form exhibit a better polymerization efficiency and an electrical conductivity one order of magnitude higher. This result is in good accordance with a higher spin density and homogeneity. It is proposed that not only are some monomers activated during the evaporation but also that the physical contact between the working electrode and the continuous carbazole films induces the growth of homogenous highly polymerized polycarbazole films. In agreement with this suggestion, the SEM study shows that this type of polycarbazole thin films keep in memory the morphology of the SnO 2 under layer. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 75: 1561–1568, 2000

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