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Mechanical and thermal behavior of polycarbonate composites reinforced with aluminum borate whiskers
Author(s) -
Tjong S. C.,
Jiang Wei
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990912)73:11<2247::aid-app22>3.0.co;2-t
Subject(s) - whisker , composite material , materials science , whiskers , thermogravimetric analysis , polycarbonate , ultimate tensile strength , composite number , chemistry , organic chemistry
Inorganic aluminum borate (Al 18 B 4 O 33 ) whisker was employed in this study to reinforce polycarbonate (PC). The composites were prepared in a single‐screw extruder, followed by injection molding. The whiskers were pretreated with tetrabutyl orthotitanate prior to compounding. The tensile, dynamic mechanical, impact, and thermal properties of the composites were studied. Tensile results showed that the modulus of PC–Al 18 B 4 O 33 composites increased markedly with increasing whisker content. However, the tensile stress of the composite decreased slightly with the addition of 5 wt % whisker; thereafter, it increased slowly with increasing whisker content. Differential thermal analysis and thermogravimetric measurements showed that the glass transition temperature ( T g ) and 5% weight loss temperature ( T −5% ) of the composite shift rapidly to lower temperature regimes with the addition of Al 18 B 4 O 33 whiskers up to 10 wt %. Thereafter, the T g and T −5% of PC–Al 18 B 4 O 33 composites tended to decrease slowly with increasing whisker content. The mechanical and thermal properties of PC–Al 18 B 4 O 33 composites were compared with those of PC–potassium titanate (K 2 Ti 6 O 13 ) whisker composites. The reinforcing effect of Al 18 B 4 O 33 and K 2 Ti 6 O 13 whiskers on PC was discussed and contrasted. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2247–2253, 1999