Premium
Effects of chemical reactions on the properties of polycarbonate/liquid crystalline polymer blends
Author(s) -
Kil Seung Bum,
Park O Ok,
Yoon Kwan Han
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990912)73:11<2123::aid-app8>3.0.co;2-6
Subject(s) - depolymerization , polycarbonate , materials science , transesterification , miscibility , rheology , polymer , reactive extrusion , polymer blend , chemical engineering , catalysis , chemical reaction , polymer chemistry , glass transition , composite material , organic chemistry , chemistry , copolymer , engineering
Effects of chemical reactions on the properties of the polycarbonate (PC)/liquid crystalline polymer (LCP) blends are considered here. Not only thermal and rheological behaviors, but also morphology and molecular weight change are investigated. Reactive blends were prepared in a cylindrical flask at 300°C with varying processing time in the presence of a catalyst by the melt‐phase reactions. For comparison, physical blends, in which chemical reactions were minimized, were also prepared at 300°C in a twin‐screw extruder. It seems that transesterification and repolymerization did not occur, but depolymerization reaction took place slightly in PC/LCP physical blends. In reactive blends, however, transesterification and repolymerization as well as depolymerization reaction took place simultaneously. The depolymerization reaction occurred mainly at an early stage of processing; whereas, repolymerization reaction becomes especially dominant after some time (more than 30 min) in the presence of the catalyst, which had a great impact on its molecular weight. Also, chemical reactions changed the glass transition temperature and morphology as well as rheological behavior, which resulted in the enhanced miscibility in reactive blends. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2123–2133, 1999