Premium
Properties of electroresponsive poly(vinyl alcohol)/poly(acrylic acid) IPN hydrogels under an electric stimulus
Author(s) -
Kim So Yeon,
Shin Heung Soo,
Lee Young Moo,
Jeong Chang Nam
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990829)73:9<1675::aid-app8>3.0.co;2-9
Subject(s) - vinyl alcohol , interpenetrating polymer network , acrylic acid , materials science , polymer chemistry , self healing hydrogels , electrolyte , ionic bonding , swelling , polymer , composite material , chemical engineering , electrode , chemistry , monomer , organic chemistry , ion , engineering
Interpenetrating polymer networks (IPNs) composed of poly(vinyl alcohol) (PVA) and poly(acrylic acid) (PAAc) exhibited electrical‐sensitive behavior. PAAc as an initial network was prepared inside a PVA solution using UV irradiation; then, PVA networks as a secondary network were formed by a repetitive freeze–thawing process. Their mechanical properties were influenced by the swelling ratio, crosslinking by UV radiation and a freeze–thawing process, and intermolecular force by hydrogen bonding. When a swollen PVA/PAAc IPN was placed between a pair of electrodes, the IPN exhibited bending behavior upon the applied electric field. The equilibrium bending angle (EBA) and the bending speed of the PVA/PAAc IPN increased with the applied voltage and the content of the PAAc network having negatively charged ionic groups within the IPN. The electroresponsive behavior of the present IPN was also affected by the electrolyte concentration of the external solution. Particularly, IPN37 showed a maximum EBA when the critical ionic strength was 0.1. Anisotropic deswelling of the IPN was observed in a direct contact with a pair of electrodes under aerobic conditions. The PVA/PAAc IPN also showed stepwise bending behavior depending on the electric stimulus. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 1675–1683, 1999