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Flocculation and coagulation of Ca‐ and K‐saturated montmorillonite in the presence of polyethylene oxide
Author(s) -
Mekhamer W. K.,
Assaad F. F.
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990801)73:5<659::aid-app6>3.0.co;2-7
Subject(s) - montmorillonite , zeta potential , flocculation , electrolyte , polyethylene , coagulation , polyethylene oxide , chemical engineering , polymer , materials science , oxide , chemistry , composite material , nanotechnology , electrode , metallurgy , psychology , psychiatry , nanoparticle , engineering
The objective of this work is to study the flocculation of Ca‐ and K‐montmorillonite in the presence of some coagulant (CaCl 2 and KCl) and mixtures of coagulants and polyethylene oxide (600,000 mol wt) through measuring the zeta potential. The action of Ca 2+ was more effective than K + in decreasing the zeta potential of Ca‐montmorillonite; consequently, the electrical double layer of the clay particles has been reduced. On the other hand, the action of K + was more pronounced than Ca 2+ in decreasing the zeta potential of K‐montmorillonite. This contradicting result was attributed to the change of the partial molal volume of Ca‐ and K‐montmorillonite. The flocculation of Ca‐ and K‐montmorillonite by polyethylene oxide was enhanced when the clay was initially treated with electrolyte. This electrolyte reduces the thickness of the electrical double layer. Under this condition, the polymer segments collapse on the clay surfaces, leaving polymer loops and tails available for contacting adjacent clay particles. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 659–662, 1999