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Graft polymerization of methyl methacrylate onto radiation‐peroxidized ultrahigh molecular weight polyethylene in the presence of metallic salt and acid
Author(s) -
Kwon Oh Hyun,
Nho Young Chang,
Jin J. H.,
Lee M. J.,
Lee Y. M.
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990502)72:5<659::aid-app6>3.0.co;2-c
Subject(s) - methyl methacrylate , polyethylene , grafting , peroxide , polymer chemistry , fourier transform infrared spectroscopy , polymerization , nuclear chemistry , sulfuric acid , materials science , dpph , chemistry , organic chemistry , chemical engineering , polymer , antioxidant , engineering
Using a radiation peroxide grafting technique, a ultrahigh molecular weight polyethylene (UHMWPE) stored at room temperature for 10 days after irradiation in air was graft copolymerized with methyl methacrylate (MMA) in the presence of metallic salt and acid. The MMA‐grafted UHMWPE samples were analyzed by measuring Fourier transform infrared spectroscopy in attenuated total reflectance (FTIR–ATR) and by electron spectroscopy for chemical analysis (ESCA). The 1,1‐diphenyl‐2‐picrylhydrzyl (DPPH) technique was utilized to evaluate the concentration of peroxide formed in the peroxidized UHMWPE samples by counting the quantity of DPPH consumed from the reaction of peroxide radicals with DPPH. It was shown that the inclusion of an FeSO 4 ·7H 2 O and sulfuric acid in MMA grafting solutions was extremely beneficial and led to a most unusual synergistic effect in the radiation‐peroxidized grafting. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 659–666, 1999