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New poly(amide‐imide) syntheses. 24. Synthesis and properties of fluorinated poly(amide‐imide)s based on 2,2‐bis[4‐(trimellitimidophenoxy)phenyl]hexafluoropropane and various aromatic diamines
Author(s) -
Yang ChinPing,
Hsiao ShengHuei,
Hsiao HsiuChun
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990131)71:5<823::aid-app17>3.0.co;2-g
Subject(s) - imide , condensation polymer , polymer chemistry , thermal stability , polyamide , triphenyl phosphite , ether , trimellitic anhydride , amide , chemistry , pyridine , materials science , glass transition , inherent viscosity , polymer , organic chemistry , intrinsic viscosity
An imide ring‐performed dicarboxylic acid bearing one hexafluoroisopropylidene and two ether linkages between aromatic rings, 2,2‐bis[4‐(4‐trimellitimidophenoxy)phenyl]hexafluoropropane (II), was prepared from the condensation of 2,2‐bis[4‐(4‐aminophenoxy)phenyl]hexafluoropropane and trimellitic anhydride. A novel series of poly(amide‐imide)s having inherent viscosities of 0.72 ∼ 1.86 dL g −1 was prepared by the triphenyl phosphite‐activated polycondensation from the diimide‐diacid (II) with various aromatic diamines in a medium consisting of N ‐methyl‐2‐pyrolidone, pyridine, and calcium chloride. Several of the resulting polymers were soluble in polar amide solvents, and their solutions could be cast into transparent, thin, flexible films having good tensile properties and high thermal stability. The 10% weight loss temperatures were all above 495°C in air or nitrogen atmosphere, and the glass transition temperatures were in the range of 237°–276°C. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 823–831, 1999