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Transesterification in homogeneous poly(ε‐caprolactone)–epoxy blends
Author(s) -
Chen JyhLuen,
Huang HuiMin,
Li MingShiu,
Chang FengChih
Publication year - 1999
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19990103)71:1<75::aid-app10>3.0.co;2-2
Subject(s) - transesterification , diglycidyl ether , epoxy , differential scanning calorimetry , polymer chemistry , materials science , bisphenol a , caprolactone , polycaprolactone , glass transition , polymer blend , chemical engineering , copolymer , polymer , organic chemistry , chemistry , composite material , methanol , physics , thermodynamics , engineering
Transesterification has been investigated in poly(ε‐caprolactone) (PCL)–epoxy blends. In the hot melt process, the hydroxyl on diglycidyl ether of bisphenol‐A (DGEBA) monomers is too low to give a noticeable transesterification reaction. In the postcure process, model reactions reveal that the hydroxyls from a ring‐opening reaction are able to react with the esters of PCL. In the meantime, the PCL molecular weight decrease and its distribution becomes broader. Nuclear magnetic resonance spectra reveal that fraction of the tertiary hydroxyls converts to secondary hydroxyls. In the cured DGEBA–3,3′‐dimethylmethylene‐di(cyclohexylamine)–PCL blend, a homogeneous morphology is achieved. PCL segments are grafted onto the epoxy network after postcuring and result in the lower T g observed in the differential scanning calorimetry thermogram. A higher transesterification extent also results in broader transition peaks by dynamic mechanical analysis. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 75–82, 1999