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Conductivity studies of solid polymer electrolytes based on polyethers and polyphosphazene blends
Author(s) -
Del Río C.,
MartínÁlvarez P. J.,
Acosta J. L.
Publication year - 1998
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19981212)70:11<2181::aid-app12>3.0.co;2-e
Subject(s) - polyphosphazene , electrolyte , conductivity , polymer blend , materials science , dielectric spectroscopy , polymer , polymer chemistry , polymer electrolytes , electrical resistivity and conductivity , conductive polymer , chemical engineering , ionic conductivity , chemistry , composite material , copolymer , electrode , physics , electrochemistry , quantum mechanics , engineering
In this work, electrical characteristics of several polymer electrolytes based on polyether and polyphosphazene blends are reported by means of complex impedance spectroscopy. In addition, a statistical analysis was conducted applying a mathematical model to a previously designed pattern to the purpose of gaining insight into the effect exerted on the conductivity of the electrolyte by the portion of each component in the blend. Evidence was obtained to prove that the dependence of conductivity on blend composition adjusts to a reduced cubic model, whose regression coefficients are determined in this work. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 70: 2181–2186, 1998