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Connectivity and spacing effects in hydrogen‐bonding polymer solutions and blends
Author(s) -
Painter Paul,
Park Yung,
Coleman Mike
Publication year - 1998
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19981114)70:7<1273::aid-app4>3.0.co;2-j
Subject(s) - copolymer , hydrogen bond , polymer , materials science , polymer science , chain (unit) , polymer chemistry , hydrogen , work (physics) , polymer blend , thermodynamics , molecule , chemistry , organic chemistry , composite material , physics , astronomy
In recent experimental work, it was found that the number of hydrogen bonds in polymer mixtures is strongly influenced by chain‐connectivity effects and the spacing of functional groups along the chain. In this article, the relationships between the equilibrium constants used to describe the number of hydrogen bonds in mixtures of various types (blends, solutions, random copolymers, etc.) is elucidated and described. © 1998 John Wiley & Sons, Inc. J. Appl. Polym. Sci. 70: 1273–1281, 1998