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Synthesis of phenetidine‐based telechelics and subsequent reactions with water‐based curing reagents
Author(s) -
Viswanathan Tito,
Helmich Janna,
Rodriguez Stephen,
Feng Qiuwei,
Toland Alan
Publication year - 1998
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19980307)67:10<1811::aid-app14>3.0.co;2-z
Subject(s) - curing (chemistry) , adhesive , epoxy , telechelic polymer , polymer chemistry , solubility , reagent , aniline , materials science , aqueous solution , formaldehyde , polyurethane , polymer science , chemistry , organic chemistry , polymer , composite material , end group , copolymer , layer (electronics)
The development of soluble telechelics based on aniline are highly desirable due to numerous applications that are possible, especially in the coatings and adhesive industry. Control of molecular length and ease of synthesis lends o ‐ethoxyaniline to be an ideal candidate for the synthesis of amino‐terminated telechelic oligomers. Combined with the higher solubility and reactivity, curing of these functionally reactive oligomers has been accomplished using aqueous formaldehyde, as well as water‐dispersed epoxy resins. Spectroscopic studies have been done to characterize the prepolymers, as well as the cured materials. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67:1811–1817, 1998