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Gamma ray‐induced copolymerization of copper (II) methacrylate: A way of access to copper‐based synthetic micro‐ and macroporous resins
Author(s) -
Baccante A.,
Quaresima R.,
Lora S.,
Palma G.,
Volpe R.,
Corain B.
Publication year - 1998
Publication title -
journal of applied polymer science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.575
H-Index - 166
eISSN - 1097-4628
pISSN - 0021-8995
DOI - 10.1002/(sici)1097-4628(19980103)67:1<11::aid-app2>3.0.co;2-r
Subject(s) - copolymer , copper , methacrylate , materials science , propane , polymer chemistry , polymer , yield (engineering) , ultraviolet , chemical engineering , chemistry , composite material , organic chemistry , metallurgy , optoelectronics , engineering
Copper methacrylate undergoes high‐yield copolymerization with hydroxi‐ethylmethacrylate in the presence of 1,1,1‐tris(hydroximethyl) propane trimethacrylate under γ‐rays irradiation at room temperature. The bluish‐green materials are characterized by bulk expanded volume measurements and infrared and ultraviolet‐visible spectroscopy, and appear to be able to slowly release an appreciable percentage of the metal center embodied in the polymer network. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 67: 11–17, 1998